Product ID:F-11,FREON 11,IROSO
MSDS Date:09/23/1991
FSC:6830
NIIN:01-040-3656
MSDS Number: BGHBS

E. I. DUPONT DE NEMOURS AND COMPANY

FREON PRODUCTS DIVISION
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637/800-424-9300(CHEMTREC)

Info Phone: 800-441-9442302-999-5072 (MSDS)

Preparer: W. J. BROCK

Cage: 73925

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

TRICHLOROFLUOROMETHANE (CFC-11) (SARA 313) (CERCLA)

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: C, 1000 PPM; 9495

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:TLV 1000 PPM (C)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, CNS, LUNGS. ACUTE-
MAY CAUSE EYE IRRITATION & BLURRING VISION. REPEATED SKIN CONTACT
CAN DRY SKIN CASING RASH. OVEREXPOSURE BY INHALATION MAY CAUSE CNS
DEPRESSION WITH ANESTHETIC E FFECTS & IRREGULAR PULSE. INGESTION
MAYCAUSE HEADACHE, NAUSEA, WEAKNESS. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DISCOMFORT, RASH, COLDNESS, DRYING,
TEARING, BLURRING OF VISION, COUGHING, IRREGULAR PULSE, DROWSINESS,
CONFUSION, HEADACHE, INCOORDINATION, LOSS OF CONSCIOUSNESS,
PALPITATION, INADEQUATE CIRCULATION, NAUSEA
Medical Cond Aggravated by Exposure:PRE-EXISTING DISEASES OF THE
CENTRAL NERVOUS SYSTEM OR CARDIOVASCULAR SYSTEM

First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE/SKIN:FLUSH
WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO
FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED. ORAL:NO SPECIFIC
INTERVENTION IS IND ICATED AS THE COMPOUND IS NOT LIKELY TOBE
HAZARDOUS BY INGESTION. HOWEVER, CONSULT A PHYSICIAN IF NECESSARY.

Flash Point Method:TCC
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE
MODE. TOXIC GASES MAY BE PRESENT.
Unusual Fire/Explosion Hazard:CONTAINERS MAY RUPTURE. DECOMPOSITION MAY
OCCUR.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. PROVIDE
VENTILATION. STOP LEAK IF POSSIBLE. DIKE SPILL. COLLECT ON
ABSORBENT MATERIAL AND TRANSFER TO STEEL DRUMS FOR RECOVERY OR
DISPOSAL. KEEP OUT OF SEWER.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE IN VENTILATED AREA AWAY FROM
EXCESSIVE HEAT, OPEN FLAMES & INCOMPATIBLES. VENTILATE LOW-LYING
AREAS OR SMALL ENCLOSURES TO PREVENT ASPHYXIATION.
Other Precautions:USE WITH SUFFICIENT VENTILATION TO KEEP EMPLOYEE
EXPOSURE BELOW RECOMMENDED LIMITS. KEEP OUT OF REACH OF CHILDREN.
WASH THOROUGHLY AFTER HANDLING. AVOID BREATHIG VAPORS.

Respiratory Protection:NONE REQUIRED FOR NORMALLY-VENTED WORK
SITUATIONS. FOR ACCIDENTAL OR NON-VENTILATED SITUATIONS, WHERE
CONCENTRATION OF VAPORS MAY BE HIGH, USE NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS OR SUPP LIED-AIR RESPIRATOR.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO
MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:NEOPRENE OR PVA
Eye Protection:SPLASH-PROOF SAFETY GOGGLES OR GLASSES
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:GOOD PERSONAL HYGIENE PRACTICES REQUIRE THAT
GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS
PRACTICAL.
Supplemental Safety and Health
"EMPTY" CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES. SEE DIRECTIONS ON
LABEL.

HCC:T6
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:75.0F,23.9C
Decomp Temp:Decomp Text:>1100F,593C
Vapor Pres:760 @ 77F
Vapor Density:4.9
Spec Gravity:1.48
Evaporation Rate & Reference:>1 (CCL4=1)
Solubility in Water:0.1% @ 77F (25C)
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH FAINT ETHEREAL ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALUMINUM POWDER, ZINC POWDER, ALKALI, ALKALINE EARTH METALS
Stability Condition to Avoid:OPEN FLAMES, EXCESSIVE HEAT, ARCS, GLOWING
METAL SURFACE
Hazardous Decomposition Products:HYDROCHLORIC ACID, HYDROFLUORIC ACID
AND POSSIBLY CARBONYL HALIDES SUCH AS PHOSGENE

Waste Disposal Methods:RECLAIM BY DISTILLATION OR REMOVE TO A PERMITTED
WASTE DISPOSAL FACILITY. COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS. DO NOT VENT TO THE ATMOSPHERE. REPORTABLE QUANTITY IS
5000 POUNDS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.